Crystal structures of two mixed-valence copper cyanide complexes withN-methylethylenediamine
نویسندگان
چکیده
منابع مشابه
Crystal structures of two mixed-valence copper cyanide complexes with N-methylethylenediamine
The crystal structures of two mixed-valence copper cyanide compounds involving N-methyl-ethylenedi-amine (meen), are described. In compound (I), poly[bis(μ3-cyanido-κ3C:C:N)tris(μ2-cyanido-κ2C:N)bis(N-methylethane-1,2-di-amine-κ2N,N')tricopper(I)copper(II)], [Cu4(CN)5(C3H10N2)2] or Cu4(CN)5meen2, cyanide groups link CuI atoms into a three-dimensional network containing open channels parallel to...
متن کاملHydrogenation of two-electron mixed-valence iridium alkyl complexes.
Two-electron mixed-valence complexes of the general formula (tfepma)(3)Ir(2)(0,II)RBr [tfepma = bis(bis(trifluoroethoxy)phosphino)methylamine, MeN[P(OCH(2)CF(3))(2)](2), and R = CH(3) (2), CH(2)C(CH(3))(3) (3)] have been synthesized and structurally characterized and their reactivity with H(2) investigated. Hydrogenation of 2 and 3 proceeds in a cascade reaction to produce alkane upon initial H...
متن کاملInvestigating vibrational relaxation in cyanide-bridged transition metal mixed-valence complexes using two-dimensional infrared and infrared pump-probe spectroscopies
Using polarization-selective two-dimensional infrared (2D IR) and infrared pump-probe spectroscopies, we study vibrational relaxation of the four cyanide stretching (νCN) vibrations found in [(NH3)5Ru(III)NCFe(II)(CN)5](-) (FeRu) dissolved in D2O or formamide and [(NC)5Fe(II)CNPt(IV)(NH3)4NCFe(II)(CN)5](4-) (FePtFe) dissolved in D2O. These cyanide-bridged transition metal complexes serve as mod...
متن کاملHydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper(I) sulfites.
Two new examples of mixed metal copper(I) sulfites, namely, Na3Mn2Cu(SO3)4(H2O)5 (1) and NaMn4Cu(SO3)5(H2O)3 (2), have been synthesized and structurally characterized. The 1D structure of 1 is built from a chain of [Mn2Cu(SO3)4]3- bridged by Na+ ions whereas the structure of 2 features a complicated 3D framework in which Mn8O36 octanuclear clusters are bridged by sulfite anions and copper(I) io...
متن کاملStructures and anti-cancer properties of two binuclear copper complexes.
The crystals of two binuclear copper-based complexes were obtained. One complex can remarkably induce apoptosis and inhibit angiogenesis to mediate tumour growth at a greater extent. Furthermore, this complex showed a strong energy-dependent and non-endocytotic uptake and exhibited multiple anti-cancer functions by inhibiting the expressions of p-Akt and p-Erk1/2 proteins and by decreasing the ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications
سال: 2017
ISSN: 2056-9890
DOI: 10.1107/s2056989017000111